Hello Jack,
from your description, it sounds like you're currently viewing the segmented structure with three materials, rather than the original gray value volume field.
Let me walk you through the full workflow I use, which might help clarify things:
1. Import the dataset via
ImportGeo-Vol. Enter all necessary parameters (like voxel size), then click on
Image Processing.
2. This opens the
3D Image Processing dialog, where you can process the images (e.g., crop, rotate, or filter), and then segment them into different materials. At this point, the gray value data is also loaded into the main GeoDict window as a
Volume Field.

3. Segment the structure using tools like
Global Thresholding or
AI Segmentation. After clicking
Create Segmentation, the segmented structure is loaded into GeoDict and visible alongside the gray value volume field.

4. With both the segmented structure and gray value data loaded, you can now compute gray value statistics for each material using
Compute Metrics. To do this, right-click the
Gray Value volume field in the
Project Status section and select
Compute Metrics.

5. In the dialog, ensure the
Gray Value field is selected. Choose which metrics to compute (e.g., Minimum, Maximum, Mean Value, Standard Deviation and Variance), then under
Values for, select
Chosen Material IDs and specify the material of interest. Click
Run to generate the statistics for the gray values of belonging to this material only.
Let me know if anything remains unclear or if you need help with a specific step.
Best regards,
Jonas